Yep, you CAN use the booth output for a second set of speakers. It would have the obvious down side of no longer having a booth speaker! Also the booth speaker is wired to NOT play the microphone sound. Now while this might be ok if you play at a venue and don’t use a mic, there is no way you are gonna get away with playing a wedding or other function without using a mic.
My advice would be to get a small PA mixer with at least 1 aux output. You can now run your controller into the PA mixer, have your master outputs with their own volume control power your PA and you can use the aux to control the second set of speakers, also with it’s own volume control.
Greetinx.